- When a gas is heated at a constant volume, the work performed on it increases the system's internal energy.
- When a gas is heated under constant pressure, work is done to overcome the pressure, and the volume expands, resulting in a rise in the system's internal energy.
- As a result,Cp
might be stated to be bigger than Cv . - Where
Cp Molar heat capacity at constant pressure, and Cv molar heat capacity at constant volume.
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